Chirality refers to objects that cannot be superimposed to their mirror images through any combination of rotations or translations, much like the distinct left and right hands of a human. In chiral crystals, the spatial arrangement of atoms confers a specific "handedness", which, for example, influences their optical and electrical properties.
The Hamburg-Oxford team focused on so-called antiferro-chirals, a type of non-chiral crystals reminiscent of antiferro-magnetic materials, in which magnetic moments anti-align in a staggered pattern leading to a vanishing net magnetization. An antiferro-chiral crystal is composed of equivalent amounts of left- and right-handed substructures in a unit cell, rendering it overall non-chiral.
The research team, led by Andrea Cavalleri, used terahertz light to lift this balance in the non-chiral material boron phosphate (BPO4), in this way inducing finite chirality on an ultrafast time scale. "We exploit a mechanism termed nonlinear phononics," says Zhiyang Zeng, lead author of this work. "By exciting a specific terahertz frequency vibrational mode, which displaces the crystal lattice along the coordinates of other modes in the material, we created a chiral state that survives for several picoseconds," he added. "Notably, by rotating the polarization of the terahertz light by 90 degrees, we could selectively induce either a left- or right-handed chiral structure," continues fellow author Michael Först.
"This discovery opens up new possibilities for the dynamical control of matter at the atomic level," says Andrea Cavalleri, group leader at the MPSD. "We are excited to see potential applications of this technology and how it can be used to create unique functionalities. The ability to induce chirality in non-chiral materials could lead to new applications in ultrafast memory devices or even more sophisticated optoelectronic platforms"
This work received financial support from the Deutsche Forschungsgemeinschaft via the Cluster of Excellence 'CUI: Advanced Imaging of Matter'. The MPSD is a member of the Center for Free-Electron Laser Science (CFEL), a joint enterprise with DESY and the University of Hamburg.
